CAS 250220-36-1|(3-Phenyl-1H-inden-1-yliden)bis(tricyclohexylphosphin)rutheniuM(IV)dichlorid

Specifikation af CAS 250220-36-1|(3-Phenyl-1H-inden-1-yliden)bis(tricyclohexylphosphin)rutheniuM(IV)dichlorid

Syntese afCAS 250220-36-1|(3-Phenyl-1H-inden-1-yliden)bis(tricyclohexylphosphin)rutheniuM(IV)dichlorid

Betingelser

Trin #1: ruthenium(III)chloridtrihydrat med triphenylphosphin i methanol i 4 timer; Inert atmosfære; Schlenk teknik;

Trin #2: 1,1-diphenyl-2-propyn-1-ol med hydrogenchlorid i tetrahydrofuran; 1,4-dioxan i 0.5h; Inert atmosfære; Schlenk teknik;

Trin #3: tricyclohexylphosphin i tetrahydrofuran; 1,4-dioxan; acetone ved -20 - 20 grad; i 10,5 timer; Opløsningsmiddel; Inert atmosfære; Schlenk teknik;

Henvisning

Polyanskii, Kirill B.; Alekseeva, Kseniia A.; Raspertov, Pavel V.; Kumandin, Pavel A.; Nikitina, Eugeniya V.; Gurbanov, Atash V.; Zubkov, Fedor I.

[Beilstein Journal of Organic Chemistry, 2019, bind. 15, s. 769 - 779]

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